Issue 70, 2024
From the journal:

Chemical Communications

Chemical synthesis of natural and azido-modified UDP-rhamnose and -arabinofuranose for glycan array-based characterization of plant glycosyltransferases†

Irene Pasini, ORCID logo a   Colin Ruprecht,a   Uwe Osswald,a   Andreas Bittmann,a   Lina Maltrovsky,a   Cecilia Romanò, ORCID logo b   Mads H. Clausen ORCID logo b  and  Fabian Pfrengle ORCID logo *a  

* Corresponding authors

a Institute of Organic Chemistry, Department of Chemistry, BOKU University, Muthgasse 18, Vienna, Austria
E-mail: Fabian.pfrengle@boku.ac.at

b Center for Nanomedicine and Theranostics, Department of Chemistry, Technical University of Denmark, Kemitorvet, Building 207, 2800 Kongens Lyngby, Denmark

Abstract

Chemical syntheses of UDP-rhamnose and UDP-arabinofuranose and respective azido-modified analogues are reported. The prepared substrates are useful for the glycan array-based analysis of glycosyltransferases, as exemplified with the plant cell wall-biosynthetic enzymes PvXAT3, AtRRT4 and PtRRT5.

Graphical abstract: Chemical synthesis of natural and azido-modified UDP-rhamnose and -arabinofuranose for glycan array-based characterization of plant glycosyltransferases

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Article information

DOI
https://doi.org/10.1039/D4CC02095B
Article type
Communication
Submitted
30 apr 2024
Accepted
26 iyl 2024
First published
29 iyl 2024

Chem. Commun., 2024,60, 9368-9371

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Chemical synthesis of natural and azido-modified UDP-rhamnose and -arabinofuranose for glycan array-based characterization of plant glycosyltransferases

I. Pasini, C. Ruprecht, U. Osswald, A. Bittmann, L. Maltrovsky, C. Romanò, M. H. Clausen and F. Pfrengle, Chem. Commun., 2024, 60, 9368 DOI: 10.1039/D4CC02095B

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