Issue 18, 2023

Surfactant stabilization of vanadium iron oxide derived from Prussian blue analog for lithium-ion battery electrodes

Abstract

Due to their high energy density, Li-ion batteries have become indispensable for energy storage in many technical devices. Prussian blue and its analogs are a versatile family of materials. Apart from their direct use as an alkali-ion battery electrode, they are a promising source for templating other compounds due to the presence of carbon, nitrogen, and metallic elements in their structure, ease of synthesis, and high tunability. In this study, homogeneous iron vanadate derivatization from iron vanadium Prussian blue was successfully carried out using an energy efficient infrared furnace utilizing CO2 gas. Iron-vanadate is an inherently unstable electrode material if cycled at low potentials vs. Li/Li+. Several parameters were optimized to achieve a stable electrochemical performance of this derivative, and the effect of surfactants, such as tannic acid, sodium dodecylbenzene sulfonate, and polyvinylpyrrolidone were shown with their role in the morphology and electrochemical performance. While stabilizing the performance, we demonstrate that the type and order of addition of these surfactants are fundamental for a successful coating formation, otherwise they can hinder the formation of PBA, which has not been reported previously. Step-by-step, we illustrate how to prepare self-standing electrodes for Li-ion battery cells without using an organic solvent or a fluorine-containing binder while stabilizing the electrochemical performance. A 400 mA h g−1 capacity at the specific current of 250 mA g−1 was achieved after 150 cycles while maintaining a Coulombic efficiency of 99.2% over an extended potential range of 0.01–3.50 V vs. Li/Li+.

Graphical abstract: Surfactant stabilization of vanadium iron oxide derived from Prussian blue analog for lithium-ion battery electrodes

Supplementary files

Article information

Article type
Paper
Submitted
04 iyl 2023
Accepted
22 iyl 2023
First published
27 iyl 2023
This article is Open Access
Creative Commons BY license

Sustainable Energy Fuels, 2023,7, 4514-4524

Surfactant stabilization of vanadium iron oxide derived from Prussian blue analog for lithium-ion battery electrodes

B. Bornamehr, H. El Gaidi, S. Arnold, E. Pameté and V. Presser, Sustainable Energy Fuels, 2023, 7, 4514 DOI: 10.1039/D3SE00854A

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

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