Issue 45, 2023

Interfacing metal organic frameworks with polymers or carbon-based materials: from simple to hierarchical porous and nanostructured composites

Abstract

In the past few years, metal organic frameworks (MOFs) have been assembled with (bio)polymers and a series of carbon-based materials (graphene, graphene oxide, carbon nanotubes, carbon quantum dots, etc.) leading to a wide range of composites differing in their chemical composition, pore structure and functionality. The objective was mainly to overcome the limitations of MOFs in terms of mechanical properties, chemical stability and processability while imparting novel functionality (electron conductivity, (photo)catalytic activity, etc.) and hierarchical porosity. These composites were considered for numerous applications including gas/liquid adsorption and separation, (photo)catalysis, biomedicine, energy storage, conversion and so on. The performance of such composites depends strongly on their microstructural and physico-chemical properties which are mainly driven by the chemical strategies used to design and process such composites. In this perspective article, we propose to cover this topic and provide a useful survey of recent progress in the synthesis and design of MOFs–carbon material composites. This article will describe the development of composites with increasing complexity in terms of porous architecture, spatial structuration and organisation, and functionality.

Graphical abstract: Interfacing metal organic frameworks with polymers or carbon-based materials: from simple to hierarchical porous and nanostructured composites

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Article information

Article type
Perspective
Submitted
17 iyl 2023
Accepted
17 okt 2023
First published
19 okt 2023
This article is Open Access

All publication charges for this article have been paid for by the Royal Society of Chemistry
Creative Commons BY license

Chem. Sci., 2023,14, 12898-12925

Interfacing metal organic frameworks with polymers or carbon-based materials: from simple to hierarchical porous and nanostructured composites

K. Dassouki, S. Dasgupta, E. Dumas and N. Steunou, Chem. Sci., 2023, 14, 12898 DOI: 10.1039/D3SC03659F

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

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