Issue 35, 2023

Photoinduced iron-catalyzed C–H alkylation of polyolefins

Abstract

Chemically introducing diverse polar groups into polyolefins via carbon–hydrogen bond alkylation with polar olefins is of substantial value in the synthesis of next-generation lightweight thermoplastics, which is still underdeveloped. In this work, we report a new approach for efficient carbon–hydrogen bond alkylation in commodity polyolefins using photoinduced iron catalysis. Various polyolefins could be functionalized with broad scope. Polar groups could be incorporated in a single step. The controllable synthesis of multi-polar functional polyolefins could be achieved by a designed module-assembled process. Remarkably, even low levels of functionalization could upcycle the polyolefin materials to exhibit unusual physical properties, such as enhancement of the transparencies, strains, stresses at break of the materials, and hydrophilicity.

Graphical abstract: Photoinduced iron-catalyzed C–H alkylation of polyolefins

Supplementary files

Article information

Article type
Edge Article
Submitted
27 iyn 2023
Accepted
03 avq 2023
First published
04 avq 2023
This article is Open Access

All publication charges for this article have been paid for by the Royal Society of Chemistry
Creative Commons BY-NC license

Chem. Sci., 2023,14, 9374-9379

Photoinduced iron-catalyzed C–H alkylation of polyolefins

Z. Zhang, Y. Zhang and R. Zeng, Chem. Sci., 2023, 14, 9374 DOI: 10.1039/D3SC03252C

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