Issue 21, 2023

Metal–organic frameworks for the photocatalytic oxygen reduction reaction to hydrogen peroxide

Abstract

The photocatalytic oxygen reduction reaction to hydrogen peroxide is an environmentally friendly and sustainable method, yet the efficient production of hydrogen peroxide tremendously depends on the light absorption and electron transfer properties of semiconductor photocatalysts. Metal–organic frameworks possess fascinating merits such as large surface area, excellent chemical stability, and tunable chemical components, which make them promising candidates for hydrogen peroxide production in various photocatalytic systems. The present review not only comprehensively elucidates the production process of hydrogen peroxide, encompassing the photocatalytic mechanism, detection method of the product, and performance evaluation, but also categorizes and summarizes the modification strategy of metal–organic frameworks in the realm of photocatalytic hydrogen peroxide production based on recent progress. Additionally, accurate fabrication strategies are given in detail to meet the development trends of metal–organic framework photocatalysts, incorporating the challenges faced.

Graphical abstract: Metal–organic frameworks for the photocatalytic oxygen reduction reaction to hydrogen peroxide

Article information

Article type
Review Article
Submitted
28 apr 2023
Accepted
09 iyl 2023
First published
12 iyl 2023

Mater. Chem. Front., 2023,7, 5120-5139

Metal–organic frameworks for the photocatalytic oxygen reduction reaction to hydrogen peroxide

X. Ji, Y. Wang and J. Tao, Mater. Chem. Front., 2023, 7, 5120 DOI: 10.1039/D3QM00468F

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