Issue 12, 2023

Recent developments in lead-free bismuth-based halide perovskite nanomaterials for heterogeneous photocatalysis under visible light

Abstract

Halide perovskite materials, especially lead-based perovskites, have been widely used for optoelectronic and catalytic applications. However, the high toxicity of the lead element is a major concern that directs the research work toward lead-free halide perovskites, which could utilize bismuth as a promising candidate. Until now, the replacement of lead by bismuth in perovskites has been well studied by designing bismuth-based halide perovskite (BHP) nanomaterials with versatile physical–chemical properties, which are emerging in various application fields, especially heterogeneous photocatalysis. In this mini-review, we present a brief overview of recent progress in BHP nanomaterials for photocatalysis under visible light. The synthesis and physical–chemical properties of BHP nanomaterials have been comprehensively summarized, including zero-dimensional, two-dimensional nanostructures and hetero-architectures. Later, we introduce the photocatalytic applications of these novel BHP nanomaterials with visible-light response, improved charge separation/transport and unique catalytic sites. Due to advanced nano-morphologies, a well-designed electronic structure and an engineered surface chemical micro-environment, BHP nanomaterials demonstrate enhanced photocatalytic performance for hydrogen generation, CO2 reduction, organic synthesis and pollutant removal. Finally, the challenges and future research directions of BHP nanomaterials for photocatalysis are discussed.

Graphical abstract: Recent developments in lead-free bismuth-based halide perovskite nanomaterials for heterogeneous photocatalysis under visible light

Article information

Article type
Minireview
Submitted
08 yan 2023
Accepted
16 fev 2023
First published
16 fev 2023

Nanoscale, 2023,15, 5598-5622

Recent developments in lead-free bismuth-based halide perovskite nanomaterials for heterogeneous photocatalysis under visible light

Z. Wu, H. Tüysüz, F. Besenbacher, Y. Dai and Y. Xiong, Nanoscale, 2023, 15, 5598 DOI: 10.1039/D3NR00124E

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