Issue 12, 2023

Isolated PdO sites on SiO2-supported NiO nanoparticles as active sites for allylic alcohol selective oxidation

Abstract

Catalytic allylic alcohol oxidation to aldehydes is an industrial process that necessitates chemoselectivity. Surface PdO (on Pd) enables this transformation but does not represent optimal metal utilisation. Here we report a facile synthesis route to produce isolated surface PdO catalytic sites on an earth-abundant metal (NiO) for cinnamyl alcohol oxidation.

Graphical abstract: Isolated PdO sites on SiO2-supported NiO nanoparticles as active sites for allylic alcohol selective oxidation

Supplementary files

Article information

Article type
Communication
Submitted
11 fev 2023
Accepted
11 may 2023
First published
12 may 2023
This article is Open Access
Creative Commons BY license

Catal. Sci. Technol., 2023,13, 3483-3488

Isolated PdO sites on SiO2-supported NiO nanoparticles as active sites for allylic alcohol selective oxidation

A. Ziarko, T. J. A. Slater, M. A. Isaacs, L. J. Durndell and C. M. A. Parlett, Catal. Sci. Technol., 2023, 13, 3483 DOI: 10.1039/D3CY00198A

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