Crystal structure engineering of metal halide perovskites for photocatalytic organic synthesis

Chunhua Wang; Yang Ding; Biao Liu; Bo Weng; Johan Hofkens; Maarten B. J. Roeffaers

doi:10.1039/D3CC00468F

Crystal structure engineering of metal halide perovskites for photocatalytic organic synthesis†

Chunhua Wang,^a Yang Ding,^b Biao Liu,

^c Bo Weng,

*^d Johan Hofkens

*^ae and Maarten B. J. Roeffaers

*^d

Author affiliations

* Corresponding authors

^a Department of Chemistry, KU Leuven, Celestijnenlaan 200F, Leuven 3001, Belgium
E-mail: johan.hofkens@kuleuven.be

^b Laboratory of Inorganic Materials Chemistry (CMI), University of Namur, 61 rue de Bruxelles, B-5000, Namur, Belgium

^c Hunan Key Laboratory for Super-microstructure and Ultrafast Process, School of Physics and Electronics, Central South University, Changsha 410083, P. R. China

^d cMACS, Department of Microbial and Molecular Systems, KU Leuven, Celestijnenlaan 200F, Leuven 3001, Belgium
E-mail: maarten.roeffaers@kuleuven.be, bo.weng@kuleuven.be

^e Max Planck Institute for Polymer Research, Ackermannweg 10, Mainz 55128, Germany

Abstract

Engineering crystal structure of Cs₃BiBr₆ and Cs₃Bi₂Br₉ is theoretically and experimentally demonstrated to modulate their photocatalytic performance. This work offers insights into the structure-photoactivity relationships of metal halide perovskites (MHPs) and provides a guideline for exploiting MHPs toward efficient photocatalytic organic synthesis.

This article is part of the themed collection: Perovskites

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Article information

DOI: https://doi.org/10.1039/D3CC00468F
Article type: Communication
Submitted: 01 fev 2023
Accepted: 15 fev 2023
First published: 15 fev 2023
This article is Open Access

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Chem. Commun., 2023,59, 3122-3125

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Crystal structure engineering of metal halide perovskites for photocatalytic organic synthesis

C. Wang, Y. Ding, B. Liu, B. Weng, J. Hofkens and M. B. J. Roeffaers, Chem. Commun., 2023, 59, 3122 DOI: 10.1039/D3CC00468F

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

Chemical Communications

Crystal structure engineering of metal halide perovskites for photocatalytic organic synthesis†

Abstract

Supplementary files

Article information

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Crystal structure engineering of metal halide perovskites for photocatalytic organic synthesis

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