Issue 15, 2023

Photocatalytic reductive C–O bond scission promoted by low-work-function Cd single atoms and clusters

Abstract

C–O bond scission via photocatalysis is an important step in biomass depolymerization. Here, we demonstrate the scission of strong ether C–O bonds promoted by low-work-function Cd single atoms and clusters. Their loading on ZnS benefits C–H bond scission, thus weakening the C–O bond for chemical bond breaking.

Graphical abstract: Photocatalytic reductive C–O bond scission promoted by low-work-function Cd single atoms and clusters

Supplementary files

Article information

Article type
Communication
Submitted
06 dek 2022
Accepted
24 yan 2023
First published
24 yan 2023

Chem. Commun., 2023,59, 2102-2105

Photocatalytic reductive C–O bond scission promoted by low-work-function Cd single atoms and clusters

L. Sun, Y. Huang, S. Liu, X. Liu, N. Luo and F. Wang, Chem. Commun., 2023, 59, 2102 DOI: 10.1039/D2CC06649A

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