Issue 12, 2023

Minisci reaction of heteroarenes and unactivated C(sp3)–H alkanes via a photogenerated chlorine radical

Abstract

Here, an efficient Minisci reaction of heteroarenes and unactivated C(sp3)–H alkanes was achieved using an inexpensive FeCl3 as a photocatalyst. The photogenerated chlorine radical contributed to the HAT of C–H and subsequently initiated this reaction. Surprisingly, salt water and even seawater can act as a chlorine radical source, which provided an enlightening idea for future organic synthesis methods.

Graphical abstract: Minisci reaction of heteroarenes and unactivated C(sp3)–H alkanes via a photogenerated chlorine radical

Supplementary files

Article information

Article type
Communication
Submitted
29 noy 2022
Accepted
13 yan 2023
First published
13 yan 2023

Chem. Commun., 2023,59, 1637-1640

Minisci reaction of heteroarenes and unactivated C(sp3)–H alkanes via a photogenerated chlorine radical

Z. Pan, L. Shen, F. W. Dagnaw, J. Zhong, J. Jian and Q. Tong, Chem. Commun., 2023, 59, 1637 DOI: 10.1039/D2CC06486C

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