Issue 37, 2022

Spin-polarized excitons and charge carriers in chiral metal halide semiconductors

Abstract

Chirality is one of the fundamental phenomena existing in nature and widely applied in many fields such as asymmetric catalysis, optoelectronic devices, biomedicine, information communication, and so on. As an emerging semiconducting material, organic–inorganic hybrid metal halides have the advantages of a high absorption coefficient, long charge diffusion length, high defect tolerance, and easy preparation. The structural and compositional diversity of metal halide semiconductors makes it possible to introduce chirality and create a new class of chiral materials that exhibit different properties from other conventional ones. Recently, chiral metal halides have attracted extensive attention mainly by incorporating chiral organic molecules into metal halide lattices. Thanks to inversion-symmetry breaking and enhanced spin–orbit coupling (SOC), excitons and charge carriers in chiral metal halides exhibit a strong spin-polarization response. Here, we summarized the chiral effects on exciton and charge behaviours in metal halide semiconductors, followed by their unique optical and electrical properties, and finally presented their (opto-)electronic applications, such as in circular-polarization photodetectors, spin-LEDs and spin valves.

Graphical abstract: Spin-polarized excitons and charge carriers in chiral metal halide semiconductors

Article information

Article type
Review Article
Submitted
20 mar 2022
Accepted
17 iyn 2022
First published
17 iyn 2022

J. Mater. Chem. A, 2022,10, 19367-19386

Spin-polarized excitons and charge carriers in chiral metal halide semiconductors

J. Xiao, H. Zheng, R. Wang, Y. Wang and S. Hou, J. Mater. Chem. A, 2022, 10, 19367 DOI: 10.1039/D2TA02207A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements