Issue 19, 2022

Photocatalytic C(sp3) radical generation via C–H, C–C, and C–X bond cleavage

Abstract

C(sp3) radicals (R˙) are of broad research interest and synthetic utility. This review collects some of the most recent advancements in photocatalytic R˙ generation and highlights representative examples in this field. Based on the key bond cleavages that generate R˙, these contributions are divided into C–H, C–C, and C–X bond cleavages. A general mechanistic scenario and key R˙-forming steps are presented and discussed in each section.

Graphical abstract: Photocatalytic C(sp3) radical generation via C–H, C–C, and C–X bond cleavage

Article information

Article type
Review Article
Submitted
12 yan 2022
Accepted
17 apr 2022
First published
18 apr 2022
This article is Open Access

All publication charges for this article have been paid for by the Royal Society of Chemistry
Creative Commons BY license

Chem. Sci., 2022,13, 5465-5504

Photocatalytic C(sp3) radical generation via C–H, C–C, and C–X bond cleavage

C. Huang, J. Li and C. Li, Chem. Sci., 2022, 13, 5465 DOI: 10.1039/D2SC00202G

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

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