Issue 47, 2022

Gas-assisted blade-coating of organic semiconductors: molecular assembly, device fabrication and complex thin-film structuring

Abstract

The competitive performance of optoelectronic devices based on advanced organic semiconductors increasingly calls for suitably scalable processing schemes to capitalise on their application potential. With performance benchmarks typically established by spin-coating fabrication, doctor-blade deposition represents a widely available roll-to-roll-compatible means for the preparation of large-area samples and establishing the device upscaling potential. However, the inherently slower film formation kinetics often result in unfavourable active layer microstructures, requiring empirical and material-inefficient optimisation of solutions to reach the performance of spin-coated devices. Here we present a versatile approach to achieving performance parity for spin- and blade-coated devices using in situ gas-assisted drying enabled by a modular 3D-printed attachment. This is illustrated for organic photodetectors (OPDs) featuring bulk heterojunction active layers comprising blends of P3HT and PM6 polymer donors with the nonfullerene acceptor ITIC. Compared to conventionally blade-coated devices, mild drying gas pressures of 0.5–2 bar yield up to a 10-fold enhancement of specific detectivity by maximising external quantum efficiency and suppressing dark-current. Furthermore, controlling gas flux distribution enables one-step fabrication of 1D chain conformation and 2D chain orientation patterns in, respectively, PFO and P3HT:N2200 blend films, opening the possibility for high-throughput fabrication of devices with complex structured active layers.

Graphical abstract: Gas-assisted blade-coating of organic semiconductors: molecular assembly, device fabrication and complex thin-film structuring

Supplementary files

Article information

Article type
Paper
Submitted
25 okt 2022
Accepted
19 noy 2022
First published
21 noy 2022
This article is Open Access
Creative Commons BY license

Nanoscale, 2022,14, 17743-17753

Gas-assisted blade-coating of organic semiconductors: molecular assembly, device fabrication and complex thin-film structuring

H. Mejri, A. Haidisch, P. Krebsbach, M. Seiberlich, G. Hernandez-Sosa and A. Perevedentsev, Nanoscale, 2022, 14, 17743 DOI: 10.1039/D2NR05947A

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