Issue 43, 2022

Design of coordination polymers based on combinations of 1,2-diphenylethane-1,2-diyl diisonicotinate with Cu(ii), Zn(ii), Cd(ii) and Co(ii)

Abstract

Five new supramolecular coordination polymers (L-Cu(acac)2, L-Cu(hfac)2, L-ZnCl2, L-CdI2 and L-CoCl2) based on the use of the flexible organic ligand L (1,2-diphenylethane-1,2-diyl diisonicotinate) combined with Cu(acac)2, Cu(hfac)2, ZnCl2, CdI2 or CoCl2 metallaligands, were synthesized and structurally characterized by single-crystal X-ray diffraction. They represent the first reported coordination polymers based on this ligand presenting ester junctions. X-ray diffraction analysis revealed the structure and the dimensionality of these coordination polymers as well as their packing in the crystal that depends on the conformation adopted by the ligand L and the nature of the used metallic salts.

Graphical abstract: Design of coordination polymers based on combinations of 1,2-diphenylethane-1,2-diyl diisonicotinate with Cu(ii), Zn(ii), Cd(ii) and Co(ii)

Supplementary files

Article information

Article type
Paper
Submitted
22 iyl 2022
Accepted
07 okt 2022
First published
07 okt 2022
This article is Open Access
Creative Commons BY-NC license

CrystEngComm, 2022,24, 7632-7639

Design of coordination polymers based on combinations of 1,2-diphenylethane-1,2-diyl diisonicotinate with Cu(II), Zn(II), Cd(II) and Co(II)

S. Zazouli, N. Gruber, V. Bulach, S. Ferlay and A. Jouaiti, CrystEngComm, 2022, 24, 7632 DOI: 10.1039/D2CE01001A

This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. You can use material from this article in other publications, without requesting further permission from the RSC, provided that the correct acknowledgement is given and it is not used for commercial purposes.

To request permission to reproduce material from this article in a commercial publication, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party commercial publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements