Issue 88, 2022

Synthesis and characterisation of an integratively self-sorted [Fe4L6]8+ tetrahedron

Abstract

Isolating metal–organic cage structures which incorporate more than one distinct ligand has been challenging due to competing pressures from narcissistic and social sorting phenomena. Here we report the first example of exclusive formation of a single tetrahedral product from a reaction mixture containing two different bidentate ligands. Exclusive formation of the tetrahedron, which incorporates one unique metal vertex, relies on a triamine to orientate the heteroditopic ligand. Inclusion of perchlorate counterions during the self-assembly process is also found to be a requirement if social sorting is to be avoided. The C3-symmetric structure is characterised by HR-MS, NMR spectroscopy and X-ray crystallography, and provides proof of principle for use of heteroditopic ligands in classical M4L6 supramolecular structures, opening exciting possibilities for their use in separation, storage and catalysis applications.

Graphical abstract: Synthesis and characterisation of an integratively self-sorted [Fe4L6]8+ tetrahedron

Supplementary files

Article information

Article type
Communication
Submitted
19 avq 2022
Accepted
10 okt 2022
First published
18 okt 2022
This article is Open Access
Creative Commons BY license

Chem. Commun., 2022,58, 12301-12304

Synthesis and characterisation of an integratively self-sorted [Fe4L6]8+ tetrahedron

L. L. K. Taylor, R. Andrews, A. C. Y. Sung, I. J. Vitorica-Yrezabal and I. A. Riddell, Chem. Commun., 2022, 58, 12301 DOI: 10.1039/D2CC04624E

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