Issue 23, 2022

New approaches to the functionalization of the 1-carba-closo-decaborate anion

Abstract

Two new approaches to the functionalization of the 1-carba-closo-decaborate anion [1-CB9H10] at boron atoms via the ring-opening of its 1,4-dioxane derivative with various nucleophiles and Pd-catalysed cross-coupling of its iodo derivative with aromatic amines and heteroaromatics were developed.

Graphical abstract: New approaches to the functionalization of the 1-carba-closo-decaborate anion

Supplementary files

Article information

Article type
Communication
Submitted
12 noy 2021
Accepted
18 fev 2022
First published
18 fev 2022

Chem. Commun., 2022,58, 3775-3778

New approaches to the functionalization of the 1-carba-closo-decaborate anion

A. V. Shmal’ko, P. Cendoya, S. A. Anufriev, K. Yu. Suponitsky, D. Gabel and I. B. Sivaev, Chem. Commun., 2022, 58, 3775 DOI: 10.1039/D1CC06395B

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