Issue 13, 2022

In situ generation of radical initiators using amine-borane complexes for carbohalogenation of alkenes

Abstract

Atom transfer radical addition of alkyl halides to alkenes was developed using a low amount of a stable initiator, amine borane complexes. Thanks to a slow hydroboration step, the overall carbohalogenation process leads to good isolated yields.

Graphical abstract: In situ generation of radical initiators using amine-borane complexes for carbohalogenation of alkenes

Supplementary files

Article information

Article type
Communication
Submitted
12 noy 2021
Accepted
17 yan 2022
First published
17 yan 2022

Chem. Commun., 2022,58, 2124-2127

In situ generation of radical initiators using amine-borane complexes for carbohalogenation of alkenes

V. Liautard, M. Delgado, B. Colin, L. Chabaud, G. Michaud and M. Pucheault, Chem. Commun., 2022, 58, 2124 DOI: 10.1039/D1CC06390A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements