Issue 1, 2021

Recent advances in layered Ln2NiO4+δ nickelates: fundamentals and prospects of their applications in protonic ceramic fuel and electrolysis cells

Abstract

In the past decade, intensive research on proton-conducting oxide materials has provided a basis for the development of intermediate-temperature protonic ceramic electrochemical cells, which constitute a real alternative to conventional cells based on oxygen-conducting electrolytes. To achieve both high efficiency and excellent performance, not only electrolytes but also electrode materials should be carefully selected considering their functional properties. Compared to the traditional ABO3 perovskite electrode materials, Ln2NiO4+δ with a layered structure has unique advantages (high chemical stability, mechanical compatibility, improved oxygen transport, and hydration ability), and thus is now becoming a hot topic in this field, offering both scientific and practical interests. However, a comprehensive and in-depth review is still lacking in the literature to date. Accordingly, this work presents a comprehensive overview of the prospects of layered nickelates (Ln2NiO4+δ, where Ln = La, Nd, and Pr) as one of the most attractive oxygen (steam) electrode materials for protonic ceramic electrochemical cells. In particular, the crystalline features, defect structure, stability, chemical properties, and mechanical compatibility of this class of materials, contributing to their transport functionality, are discussed with the primary emphasis on revealing the relationship between the composition of the materials and their properties. The presented systematic results reveal the main strategies regarding the utilisation of Ln2NiO4+δ-based electrodes and existing gaps related to fundamental and applied research aspects.

Graphical abstract: Recent advances in layered Ln2NiO4+δ nickelates: fundamentals and prospects of their applications in protonic ceramic fuel and electrolysis cells

Supplementary files

Article information

Article type
Review Article
Submitted
19 avq 2020
Accepted
06 noy 2020
First published
08 dek 2020

J. Mater. Chem. A, 2021,9, 154-195

Recent advances in layered Ln2NiO4+δ nickelates: fundamentals and prospects of their applications in protonic ceramic fuel and electrolysis cells

A. P. Tarutin, J. G. Lyagaeva, D. A. Medvedev, L. Bi and A. A. Yaremchenko, J. Mater. Chem. A, 2021, 9, 154 DOI: 10.1039/D0TA08132A

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