Issue 40, 2021

Water-stable hydrazone-linked porous organic cages

Abstract

Although porous organic cages (POCs), particularly imine-linked (C[double bond, length as m-dash]N) ones, have advanced significantly over the last few decades, the reversible nature of imine linkages makes them prone to hydrolysis and structural collapse, severely limiting their applications under moist or water conditions. Herein, seven water-stable hydrazone-linked (C[double bond, length as m-dash]N–N) POCs are prepared through a simple coupling of the same supramolecular tetraformylresorcin[4]arene cavitand with different dihydrazide linkers. Their structures are all determined by single-crystal X-ray crystallography, demonstrating rich structural diversity from the [2 + 4] lantern, [3 + 6] triangular prism, and unprecedented [4 + 8] square prism to the extra-large [6 + 12] octahedron. In addition, they respectively exhibit tunable window diameters and cavity volumes ranging from about 5.4 to 11.1 nm and 580 to 6800 Å3. Moreover, their application in the water environment for pollutant removal was explored, indicating that they can effectively eliminate various types of contaminants from water, including radionuclide waste, toxic heavy metal ions, and organic micropollutants. This work demonstrates a convenient method for rationally constructing versatile robust POCs and presents their great application potentialities in water medium.

Graphical abstract: Water-stable hydrazone-linked porous organic cages

Supplementary files

Article information

Article type
Edge Article
Submitted
17 avq 2021
Accepted
23 sen 2021
First published
23 sen 2021
This article is Open Access

All publication charges for this article have been paid for by the Royal Society of Chemistry
Creative Commons BY-NC license

Chem. Sci., 2021,12, 13307-13315

Water-stable hydrazone-linked porous organic cages

M. Yang, F. Qiu, E. M. El-Sayed, W. Wang, S. Du, K. Su and D. Yuan, Chem. Sci., 2021, 12, 13307 DOI: 10.1039/D1SC04531H

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