Issue 14, 2021

Pillar[5]arene-based ion-pair recognition for constructing a [2]pseudorotaxane with supramolecular interaction induced LCST behavior

Abstract

A LCST-type [2]pseudorotaxane based on perbromoethylated pillar[5]arene/imidazolium iodide ionic liquid ion-pair recognition is constructed in both solution and the solid state. The thermo-responsive behavior can be adjusted by altering the molar ratio of the host and guest as well as the concentrations of these two components in solution.

Graphical abstract: Pillar[5]arene-based ion-pair recognition for constructing a [2]pseudorotaxane with supramolecular interaction induced LCST behavior

Supplementary files

Article information

Article type
Research Article
Submitted
23 mar 2021
Accepted
04 may 2021
First published
10 may 2021

Org. Chem. Front., 2021,8, 3675-3680

Pillar[5]arene-based ion-pair recognition for constructing a [2]pseudorotaxane with supramolecular interaction induced LCST behavior

M. Li, B. Hua and F. Huang, Org. Chem. Front., 2021, 8, 3675 DOI: 10.1039/D1QO00457C

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