Issue 5, 2021

Dinuclear anthracene-containing alkynylplatinum(ii) terpyridine complexes with photo-modulated self-assembly behaviors

Abstract

A new series of dinuclear anthracene-containing alkynylplatinum(II) terpyridine complexes exhibited intriguing photo-modulated self-assembly behaviors in solutions. Facilitated by Pt⋯Pt, π–π stacking and hydrophobic interactions, supramolecular assemblies have been formed in their DMSO solutions, featuring interesting spectroscopic responses accompanied by drastic color changes upon varying temperature, and distinct supramolecular nanostructures. Interestingly, these complexes can undergo photooxygenation upon UV excitation, which has been shown to alter their self-assembly behaviors, as revealed by the corresponding electron microscopic and DLS studies before and after photoirradiation.

Graphical abstract: Dinuclear anthracene-containing alkynylplatinum(ii) terpyridine complexes with photo-modulated self-assembly behaviors

Supplementary files

Article information

Article type
Research Article
Submitted
23 noy 2020
Accepted
12 yan 2021
First published
25 yan 2021

Mater. Chem. Front., 2021,5, 2409-2415

Dinuclear anthracene-containing alkynylplatinum(II) terpyridine complexes with photo-modulated self-assembly behaviors

S. Fang, M. H. Chan and V. W. Yam, Mater. Chem. Front., 2021, 5, 2409 DOI: 10.1039/D0QM00972E

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