Issue 34, 2021

Surface overgrowth on gold nanoparticles modulating high-energy facets for efficient electrochemical CO2 reduction

Abstract

Electrochemical CO2 reduction reaction (eCO2RR) has been considered one of the potential technologies to store electricity from renewable energy sources into chemical energy. For this aim, designing catalysts with high surface activities is critical for effective eCO2RR. In this study, we introduced a surface overgrowth method on stable Au icosahedrons to generate Au nanostars with large bumps. As a catalyst for eCO2RR, the Au nanostars exhibited a maximum faradaic efficiency (FE) of 98% and a mass activity of 138.9 A g−1 for CO production, where the latter was one of the highest activities among Au catalysts. Despite the deducted electrochemically active surface area per mass, the high-energy surfaces from overgrowth provided a 3.8-fold larger specific activity than the original Au icosahedral seeds, resulting in superior eCO2RR performances that outweigh the trade-off of size and shape in nanoparticles. The Au nanostars also represented prolonged stability due to the durability of high-energy facets. The characterization of surface morphology and density functional theory calculations revealed that predominant Au(321) facets on the Au nanostars effectively stabilized *COOH adsorbates, thus lowering the overpotential and improving the FE for CO production. This overgrowth method is simple and universal for various materials, which would be able to extend into a wide range of electrochemical catalysts.

Graphical abstract: Surface overgrowth on gold nanoparticles modulating high-energy facets for efficient electrochemical CO2 reduction

Supplementary files

Article information

Article type
Paper
Submitted
17 iyn 2021
Accepted
07 avq 2021
First published
09 avq 2021

Nanoscale, 2021,13, 14346-14353

Surface overgrowth on gold nanoparticles modulating high-energy facets for efficient electrochemical CO2 reduction

W. Choi,, J. W. Park, W. Park, Y. Jung and H. Song, Nanoscale, 2021, 13, 14346 DOI: 10.1039/D1NR03928H

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