Issue 37, 2021

Insights into the past and future of Janus-di-N-heterocyclic carbenes

Abstract

Janus di-N-heterocyclic carbene (NHC) ligands are a subclass of poly-NHCs that feature coordination to two transition metals in a facially opposed manner. The combination of the structural features of Janus type ligands, with the properties conferred by the NHC ligands, has conferred Janus-di-NHCs with privileged attributes for their use in diverse areas of research, such as homogeneous catalysis, materials chemistry and supramolecular chemistry. In molecular chemistry, Janus di-NHCs constitute one of the most useful chemical platforms for constructing dimetallic structures, and this includes both homo- and hetero-dimetallic compounds. This review aims to cover the most relevant advances in the use of Janus-di-NHCs during the last 15 years, by classifying them according to their specific structural features.

Graphical abstract: Insights into the past and future of Janus-di-N-heterocyclic carbenes

Article information

Article type
Perspective
Submitted
18 iyn 2021
Accepted
18 iyl 2021
First published
19 iyl 2021

Dalton Trans., 2021,50, 12748-12763

Insights into the past and future of Janus-di-N-heterocyclic carbenes

M. Poyatos and E. Peris, Dalton Trans., 2021, 50, 12748 DOI: 10.1039/D1DT02035H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements