Issue 73, 2021

Slow magnetic relaxation in distorted tetrahedral Dy(iii) aryloxide complexes

Abstract

Three distorted tetrahedral Dy(III) aryloxide complexes, [Na(THF)6][Dy(OArAd2tBu)2Cl2] (1) (OArAd2tBu = OC6H2Adamantyl2-2,6-tBu-4) and [Na(THF)6][Dy(OMes*)3X] (X = Cl, 2; BH4, 3), (OMes* = OC6H2tBu3-2,4,6) exhibit easy axis magnetic anisotropy and slow magnetic relaxation at zero field, with relaxation rates 1 < 2 < 3.

Graphical abstract: Slow magnetic relaxation in distorted tetrahedral Dy(iii) aryloxide complexes

Supplementary files

Article information

Article type
Communication
Submitted
23 may 2021
Accepted
12 avq 2021
First published
12 avq 2021
This article is Open Access
Creative Commons BY license

Chem. Commun., 2021,57, 9208-9211

Slow magnetic relaxation in distorted tetrahedral Dy(III) aryloxide complexes

V. S. Parmar, G. K. Gransbury, G. F. S. Whitehead, D. P. Mills and R. E. P. Winpenny, Chem. Commun., 2021, 57, 9208 DOI: 10.1039/D1CC02707G

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