Issue 2, 2020

A stable covalent organic framework for photocatalytic carbon dioxide reduction

Abstract

Photocatalytic conversion of CO2 into fuels is an important challenge for clean energy research and has attracted considerable interest. Here we show that tethering molecular catalysts—a rhenium complex, [Re(bpy)(CO)3Cl]—together in the form of a crystalline covalent organic framework (COF) affords a heterogeneous photocatalyst with a strong visible light absorption, a high CO2 binding affinity, and ultimately an improved catalytic performance over its homogeneous Re counterpart. The COF incorporates bipyridine sites, allowing for ligation of the Re complex, into a fully π-conjugated backbone that is chemically robust and promotes light-harvesting. A maximum rate of 1040 μmol g−1 h−1 for CO production with 81% selectivity was measured. CO production rates were further increased up to 1400 μmol g−1 h−1, with an improved selectivity of 86%, when a photosensitizer was added. Addition of platinum resulted in production of syngas, hence, the co-formation of H2 and CO, the chemical composition of which could be adjusted by varying the ratio of COF to platinum. An amorphous analog of the COF showed significantly lower CO production rates, suggesting that crystallinity of the COF is beneficial to its photocatalytic performance in CO2 reduction.

Graphical abstract: A stable covalent organic framework for photocatalytic carbon dioxide reduction

Supplementary files

Article information

Article type
Edge Article
Submitted
31 iyl 2019
Accepted
20 noy 2019
First published
21 noy 2019
This article is Open Access

All publication charges for this article have been paid for by the Royal Society of Chemistry
Creative Commons BY license

Chem. Sci., 2020,11, 543-550

A stable covalent organic framework for photocatalytic carbon dioxide reduction

Z. Fu, X. Wang, A. M. Gardner, X. Wang, S. Y. Chong, G. Neri, A. J. Cowan, L. Liu, X. Li, A. Vogel, R. Clowes, M. Bilton, L. Chen, R. S. Sprick and A. I. Cooper, Chem. Sci., 2020, 11, 543 DOI: 10.1039/C9SC03800K

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

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