Issue 53, 2020

Salt nanoconfinement in zirconium-based metal–organic frameworks leads to pore-size and loading-dependent ionic conductivity enhancement

Abstract

The effect of nanoscale confinement of a salt on its ionic conductivity was studied for [NEt4][TFSI] melt-loaded in three isoreticular zirconium-based MOFs: UiO-66, UiO-67, and PCN-56. Conductivity of the MOF-salt composites was up to a factor of 50 higher than the pure salt, and maximized with slightly less than full loading of the MOFs.

Graphical abstract: Salt nanoconfinement in zirconium-based metal–organic frameworks leads to pore-size and loading-dependent ionic conductivity enhancement

Supplementary files

Article information

Article type
Communication
Submitted
01 may 2020
Accepted
22 may 2020
First published
01 iyn 2020

Chem. Commun., 2020,56, 7245-7248

Author version available

Salt nanoconfinement in zirconium-based metal–organic frameworks leads to pore-size and loading-dependent ionic conductivity enhancement

S. Shalini, T. P. Vaid and A. J. Matzger, Chem. Commun., 2020, 56, 7245 DOI: 10.1039/D0CC03147J

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements