Issue 59, 2020

Unexpected reactivity of a PONNOP ‘expanded pincer’ ligand

Abstract

We report the synthesis, characterization and coordination chemistry of a new naphthyridine-derived phosphinite PONNOP expanded pincer ligand. As envisioned, the dinucleating ligand readily binds two copper(I) centers in close proximity, but undergoes an unexpected rearrangement in the presence of nickel(II) salts to form an interesting PONNP pincer platform.

Graphical abstract: Unexpected reactivity of a PONNOP ‘expanded pincer’ ligand

Supplementary files

Article information

Article type
Communication
Submitted
24 mar 2020
Accepted
29 apr 2020
First published
01 may 2020
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2020,56, 8198-8201

Unexpected reactivity of a PONNOP ‘expanded pincer’ ligand

A. R. Scheerder, M. Lutz and D. L. J. Broere, Chem. Commun., 2020, 56, 8198 DOI: 10.1039/D0CC02166K

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