Issue 7, 2019

The photoluminescence mechanism of CsPb2Br5 microplates revealed by spatially resolved single particle spectroscopy

Abstract

CsPb2Br5 is a new member of the all-inorganic lead halide perovskite family with unique structures and optoelectronic properties for various applications. As an indirect band gap semiconductor, the photoluminescence (PL) mechanism of CsPb2Br5 is still under debate. To resolve this issue, CsPb2Br5 microplates with strong green PL have been prepared by a hot-injection method. Characterization by transmission electron microscopy (TEM), X-ray diffraction (XRD) analysis and ultraviolet-visible (UV-vis) absorption spectroscopy indicates the existence of a small amount of embedded CsPbBr3 phase. The removal of the embedded CsPbBr3 phase by treatment with water containing ethanol solvent resulted in complete PL quenching, suggesting the origin of PL due to the embedded CsPbBr3 phase. Spatially resolved PL and time-resolved PL mapping have been further employed to directly visualize the spatial distribution of different emission centers. Our single particle spectroscopic studies indicated the existence of three different emission centers with different PL lifetimes: two types of embedded CsPbBr3 phases (clumped and randomly distributed CsPbBr3 nanocrystals) and intrinsic defects of CsPb2Br5. The embedded CsPbBr3 phases with fast and intermediate PL lifetimes are the primary contributors to PL of the CsPb2Br5 microplates while their intrinsic defects with slow PL lifetimes make only a minor contribution. These studies have unambiguously clarified the PL mechanisms of the CsPb2Br5 microplates and provided the direct mapping of different emission centers, which resolve the contradictory explanation and debate about the PL mechanism of the CsPb2Br5 microplates.

Graphical abstract: The photoluminescence mechanism of CsPb2Br5 microplates revealed by spatially resolved single particle spectroscopy

Supplementary files

Article information

Article type
Paper
Submitted
14 dek 2018
Accepted
21 yan 2019
First published
22 yan 2019

Nanoscale, 2019,11, 3186-3192

The photoluminescence mechanism of CsPb2Br5 microplates revealed by spatially resolved single particle spectroscopy

T. Zhang, Z. Chen, Y. Shi and Q. Xu, Nanoscale, 2019, 11, 3186 DOI: 10.1039/C8NR10110H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements