Threshold photoelectron spectrum of the CH2OO Criegee intermediate

David V. Chicharro; Sonia Marggi Poullain; Luis Bañares; Helgi Rafn Hrodmarsson; Gustavo A. García; Jean-Christophe Loison

doi:10.1039/C9CP02538C

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Threshold photoelectron spectrum of the CH₂OO Criegee intermediate†

David V. Chicharro,

^a Sonia Marggi Poullain,

^b Luis Bañares,

*^a Helgi Rafn Hrodmarsson,^c Gustavo A. García

*^c and Jean-Christophe Loison

*^d

Author affiliations

* Corresponding authors

^a Departamento de Química Física, Facultad de Ciencias Químicas, Universidad Complutense de Madrid, 28040 Madrid, Spain

^b Departamento de Química, Módulo 13, Facultad de Ciencias, Universidad Autónoma de Madrid, 28049 Madrid, Spain

^c Synchrotron SOLEIL, L’Orme des Merisiers, St. Aubin, BP 48, 91192 Gif sur Yvette, France
E-mail: garcia@synchrotron-soleil.fr

^d ISM, Université Bordeaux 1, CNRS, 351 cours de la Libération, 33405 Talence Cedex, France

Abstract

We present the photoelectron spectroscopy of the simplest Criegee intermediate, CH₂OO, close to the first ionization energy. Comparison with existing theoretical data yields the experimental adiabatic ionization energy and provides a benchmark for theoretical studies on larger Criegee intermediates, which play an important role in the ozonolysis of alkenes.

This article is part of the themed collection: 2019 PCCP HOT Articles

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Article information

DOI: https://doi.org/10.1039/C9CP02538C
Article type: Communication
Submitted: 07 may 2019
Accepted: 03 iyn 2019
First published: 03 iyn 2019

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Phys. Chem. Chem. Phys., 2019,21, 12763-12766

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Threshold photoelectron spectrum of the CH₂OO Criegee intermediate

D. V. Chicharro, S. M. Poullain, L. Bañares, H. R. Hrodmarsson, G. A. García and J. Loison, Phys. Chem. Chem. Phys., 2019, 21, 12763 DOI: 10.1039/C9CP02538C

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