Issue 37, 2019

Redox-responsive phosphonite gold complexes in hydroamination catalysis

Abstract

Very high activities were observed in the redox-induced hydroamination of alkynes by employing a redox-active gold(I) complex featuring an electron-deficient, terphenyl-substituted phosphonite-based ligand. The hydroamination proceeds roughly two-fold faster with the in situ oxidized catalysts than with their reduced form.

Graphical abstract: Redox-responsive phosphonite gold complexes in hydroamination catalysis

Supplementary files

Article information

Article type
Communication
Submitted
21 fev 2019
Accepted
20 mar 2019
First published
20 mar 2019
This article is Open Access
Creative Commons BY license

Chem. Commun., 2019,55, 5323-5326

Redox-responsive phosphonite gold complexes in hydroamination catalysis

E. Deck, H. E. Wagner, J. Paradies and F. Breher, Chem. Commun., 2019, 55, 5323 DOI: 10.1039/C9CC01492F

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