Issue 32, 2019

Gold(ii) in redox-switchable gold(i) catalysis

Abstract

Gold(II) species catalyse the cyclisation of N(2-propyn-1-yl)benzamide to 2-phenyl-5-vinylidene-2-oxazoline without halide abstraction while the saturated gold(I) complex is inactive. Redox-switching between gold(II) and gold(I) turns catalytic turnover on and off.

Graphical abstract: Gold(ii) in redox-switchable gold(i) catalysis

Supplementary files

Article information

Article type
Communication
Submitted
11 yan 2019
Accepted
01 mar 2019
First published
01 mar 2019

Chem. Commun., 2019,55, 4615-4618

Gold(II) in redox-switchable gold(I) catalysis

P. Veit, C. Volkert, C. Förster, V. Ksenofontov, S. Schlicher, M. Bauer and K. Heinze, Chem. Commun., 2019, 55, 4615 DOI: 10.1039/C9CC00283A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements