Glucose isomerization catalyzed by bone char and the selective production of 5-hydroxymethylfurfural in aqueous media

Babasaheb M. Matsagar; Chi Van Nguyen; Md. Shahriar A. Hossain; Md. Tofazzal Islam; Yusuke Yamauchi; Paresh L. Dhepe; Kevin C.-W. Wu

doi:10.1039/C8SE00339D

Glucose isomerization catalyzed by bone char and the selective production of 5-hydroxymethylfurfural in aqueous media†

Babasaheb M. Matsagar,

^a Chi Van Nguyen,^a Md. Shahriar A. Hossain,^bc Md. Tofazzal Islam,^d Yusuke Yamauchi,

^befg Paresh L. Dhepe

^h and Kevin C.-W. Wu

*^a

Author affiliations

* Corresponding authors

^a Department of Chemical Engineering, National Taiwan University, No. 1, Sec. 4, Roosevelt Road, Taipei 10617, Taiwan
E-mail: kevinwu@ntu.edu.tw

^b College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042, China

^c School of Mechanical & Mining Engineering, The University of Queensland, Brisbane, QLD 4072, Australia

^d Department of Biotechnology, Bangabandhu Sheikh Mujibur Rahman Agricultural University, Gazipur 1706, Bangladesh

^e School of Chemical Engineering and Australian Institute for Bioengineering and Nanotechnology (AIBN), The University of Queensland, Brisbane, QLD 4072, Australia

^f International Center for Materials Nanoarchitectonics (WPI-MANA), National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044, Japan

^g Department of Plant & Environmental New Resources, Kyung Hee University, 1732 Deogyeong-daero, Giheung-gu, Yongin-si, Gyeonggi-do 446-701, South Korea

^h Catalysis & Inorganic Chemistry Division, CSIR-National Chemical Laboratory, Dr Homi Bhabha Road, Pune 411 008, India

Abstract

The selective production of 5-hydroxymethylfurfural (HMF) is important, and it is difficult with glucose substrates in a water solvent. Here we demonstrate a selective method for glucose-to-HMF conversion using the combined catalysis of bone char and 1-methyl-3-(3-sulfopropyl)-imidazolium hydrogen sulfate acidic ionic liquid catalysts with a high HMF selectivity (54%) in water.

This article is part of the themed collection: 2018 Sustainable Energy and Fuels HOT Articles

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Article information

DOI: https://doi.org/10.1039/C8SE00339D
Article type: Communication
Submitted: 10 iyl 2018
Accepted: 30 avq 2018
First published: 30 avq 2018

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Sustainable Energy Fuels, 2018,2, 2148-2153

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Glucose isomerization catalyzed by bone char and the selective production of 5-hydroxymethylfurfural in aqueous media

Babasaheb M. Matsagar, C. Van Nguyen, Md. S. A. Hossain, Md. T. Islam, Y. Yamauchi, P. L. Dhepe and K. C.-W. Wu, Sustainable Energy Fuels, 2018, 2, 2148 DOI: 10.1039/C8SE00339D

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Sustainable Energy & Fuels

Glucose isomerization catalyzed by bone char and the selective production of 5-hydroxymethylfurfural in aqueous media†

Abstract

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Glucose isomerization catalyzed by bone char and the selective production of 5-hydroxymethylfurfural in aqueous media

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