Issue 35, 2018

Combined reversible switching of ECD and quenching of CPL with chiral fluorescent macrocycles

Abstract

Straightforward synthesis and resolution of a series of chiral fluorescent macrocycles are presented, together with their electronic circular dichroism (ECD), strong excimer fluorescence (EF, λ 300 to 650 nm) and allied highly circularly polarized luminescence (CPL, glum up to 1.7 × 10−2). The ECD, EF and CPL responses are strongly affected by the presence of metal ions (Na+, Ba2+) thanks to deep conformational changes. While ECD signals can be almost completely reversibly inverted upon the complexation/decomplexation of metal ions in a typical binary response, CPL signals are reversibly quenched concomitantly. The designed macrocycles display thus a remarkable combination of both +/− ECD and on/off CPL reversible switching.

Graphical abstract: Combined reversible switching of ECD and quenching of CPL with chiral fluorescent macrocycles

Supplementary files

Article information

Article type
Edge Article
Submitted
03 iyl 2018
Accepted
30 iyl 2018
First published
01 avq 2018
This article is Open Access

All publication charges for this article have been paid for by the Royal Society of Chemistry
Creative Commons BY license

Chem. Sci., 2018,9, 7043-7052

Combined reversible switching of ECD and quenching of CPL with chiral fluorescent macrocycles

A. Homberg, E. Brun, F. Zinna, S. Pascal, M. Górecki, L. Monnier, C. Besnard, G. Pescitelli, L. Di Bari and J. Lacour, Chem. Sci., 2018, 9, 7043 DOI: 10.1039/C8SC02935K

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

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