Issue 9, 2018

Tri- and di-fluoroethylation of alkenes by visible light photoredox catalysis

Abstract

The tri- and di-fluoroethylation of alkenes with sulfonium salts, (Ph2S+CH2RF TfO) (RF = CF3 or HCF2), by visible light photoredox catalysis to give tri-/di-fluoroethyl alkenes or methoxytri-/di-fluoroethylation products are described. It was found that varying the reaction solvent led to changes in the reaction path.

Graphical abstract: Tri- and di-fluoroethylation of alkenes by visible light photoredox catalysis

Supplementary files

Article information

Article type
Research Article
Submitted
25 yan 2018
Accepted
05 mar 2018
First published
06 mar 2018

Org. Chem. Front., 2018,5, 1452-1456

Tri- and di-fluoroethylation of alkenes by visible light photoredox catalysis

X. Pan, Y. Zhao, H. Qu, J. Lin, X. Hang and J. Xiao, Org. Chem. Front., 2018, 5, 1452 DOI: 10.1039/C8QO00082D

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