Issue 10, 2018

Moving corrole towards a red-record: synthesis of β-acrolein Ga and Cu corroles using the Vilsmeier reaction

Abstract

Copper and gallium β-acrolein corroles have been obtained by reaction of corrole complexes with 3-(dimethylamino)-acrolein/phosphoryl chloride (3-DMA/POCl3) under Vilsmeier conditions. In the case of the Ga complex, up to four acroleyl substituents have been introduced at the β-peripheral positions of the corrole macrocycle. The introduction of the acroleyl moiety on the corrole scaffold strongly influences the photophysical behaviour of the Ga corroles.

Graphical abstract: Moving corrole towards a red-record: synthesis of β-acrolein Ga and Cu corroles using the Vilsmeier reaction

Supplementary files

Article information

Article type
Paper
Submitted
30 noy 2017
Accepted
04 mar 2018
First published
05 mar 2018

New J. Chem., 2018,42, 8200-8206

Moving corrole towards a red-record: synthesis of β-acrolein Ga and Cu corroles using the Vilsmeier reaction

A. Savoldelli, S. Nardis, D. Genovese, L. Prodi, F. R. Fronczek, K. M. Smith and R. Paolesse, New J. Chem., 2018, 42, 8200 DOI: 10.1039/C7NJ04705C

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