Issue 31, 2018

Chiral Cu(ii), Co(ii) and Ni(ii) complexes based on 2,2′-bipyridine modified peptoids

Abstract

Helical peptoids bearing 2,2′-bipyridine, varied in their chiral bulky side chains and their N-terminus form complexes with Cu(II), Co(II) and Ni(II) via intramolecular binding. Chiral induction from the peptoid to each metal center could be only observed in some cases and is dependent on the identity of the N-terminus and on its position relative to the metal center.

Graphical abstract: Chiral Cu(ii), Co(ii) and Ni(ii) complexes based on 2,2′-bipyridine modified peptoids

Supplementary files

Article information

Article type
Paper
Submitted
04 apr 2018
Accepted
01 iyl 2018
First published
02 iyl 2018

Dalton Trans., 2018,47, 10767-10774

Chiral Cu(II), Co(II) and Ni(II) complexes based on 2,2′-bipyridine modified peptoids

M. Baskin and G. Maayan, Dalton Trans., 2018, 47, 10767 DOI: 10.1039/C8DT01308J

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