Issue 50, 2018

Well defined difluorogold(iii) complexes supported by N-ligands

Abstract

Stable difluorogold(III) complexes can be easily synthesized either via oxidation of N-ligated cationic Au(I) precursors using XeF2 or from tricationic Au(III) precursors by displacement of the N-ligands using fluoride from economical KF. X-ray crystallographic studies of the bisimidazole ligated derivative shows the shortest Au–F bond known in a gold complex.

Graphical abstract: Well defined difluorogold(iii) complexes supported by N-ligands

Supplementary files

Article information

Article type
Communication
Submitted
29 mar 2018
Accepted
12 apr 2018
First published
12 apr 2018

Chem. Commun., 2018,54, 6832-6834

Well defined difluorogold(III) complexes supported by N-ligands

M. Albayer, R. Corbo and J. L. Dutton, Chem. Commun., 2018, 54, 6832 DOI: 10.1039/C8CC02535E

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