Issue 18, 2018

Photoredox generation of the trifluoromethyl radical from borate complexes via single electron reduction

Abstract

A method for the generation of the CF3 radical from CF3-substituted borate complexes bearing a pyridine-N-oxide ligand is described. Cleavage of the C–B bond occurs via single electron reduction by a Cu(I) photocatalyst activated by visible light.

Graphical abstract: Photoredox generation of the trifluoromethyl radical from borate complexes via single electron reduction

Supplementary files

Article information

Article type
Communication
Submitted
11 yan 2018
Accepted
05 fev 2018
First published
05 fev 2018

Chem. Commun., 2018,54, 2236-2239

Photoredox generation of the trifluoromethyl radical from borate complexes via single electron reduction

V. O. Smirnov, A. S. Maslov, V. A. Kokorekin, A. A. Korlyukov and A. D. Dilman, Chem. Commun., 2018, 54, 2236 DOI: 10.1039/C8CC00245B

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