Issue 3, 2017

Dicyanopyrazine capped with tetraphenylethylene: polymorphs with high contrast luminescence as organic volatile sensors

Abstract

Recently the polymorphism and phase-transition between polymorphs have attracted special attention in organic luminescent materials. In this report, we employed propeller-like tetraphenylethylenes to functionalize large conjugated and electron-withdrawing dicyanopyrazine units, constructing novel organic luminescent polymorphs with high contrast fluorescence. Through an in-depth study of the luminescence-related properties, the more planar structured 2DQCN was found to generate close intermolecular packing and demonstrated essentially different solid state luminescence behaviour compared with that of 1DQCN. It shows crystallization-induced red-shift fluorescence, in contrast to the crystallization-induced blue-shift of 1DQCN and many other AIE (aggregation-induced emission) materials. The morphology transformation of 2DQCN can be realized via solvent fuming and thermal annealing, where the transformation among its three forms was manifested by DSC measurements. Utilizing the high contrast luminescence of 2DQCN polymorphs, we demonstrated their real applications as selective visual sensors for detecting volatile organic compounds. The results, revealing insights into the structure–property relationship of luminescent polymorphs, should provide useful directions for the understanding, design and utilization of luminescent colour-switching materials.

Graphical abstract: Dicyanopyrazine capped with tetraphenylethylene: polymorphs with high contrast luminescence as organic volatile sensors

Supplementary files

Article information

Article type
Research Article
Submitted
28 iyl 2016
Accepted
04 sen 2016
First published
12 sen 2016

Mater. Chem. Front., 2017,1, 530-537

Dicyanopyrazine capped with tetraphenylethylene: polymorphs with high contrast luminescence as organic volatile sensors

C. Ge, Y. Liu, X. Ye, X. Zheng, Q. Han, J. Liu and X. Tao, Mater. Chem. Front., 2017, 1, 530 DOI: 10.1039/C6QM00146G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements