Issue 6, 2017

N2O-Free single-pot conversion of cyclohexane to adipic acid catalysed by an iron(ii) scorpionate complex

Abstract

The highly efficient eco-friendly synthesis of adipic acid (96% yield, 98% selectivity, TONs up to 1.8 × 103) directly from cyclohexane is achieved by using ozone and [FeCl23-HC(pz)3}] (pz = pyrazol-1-yl) in a solvent-, heating-, radiation- and N2O-free new protocol.

Graphical abstract: N2O-Free single-pot conversion of cyclohexane to adipic acid catalysed by an iron(ii) scorpionate complex

Supplementary files

Article information

Article type
Communication
Submitted
21 noy 2016
Accepted
02 yan 2017
First published
04 yan 2017

Green Chem., 2017,19, 1499-1501

N2O-Free single-pot conversion of cyclohexane to adipic acid catalysed by an iron(II) scorpionate complex

A. P. C. Ribeiro, L. M. D. R. S. Martins and A. J. L. Pombeiro, Green Chem., 2017, 19, 1499 DOI: 10.1039/C6GC03208G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements