Issue 1, 2015

Recent applications of chiral N-tert-butanesulfinyl imines, chiral diene ligands and chiral sulfur–olefin ligands in asymmetric synthesis

Abstract

This review highlights the recent applications of chiral N-tert-butanesulfinyl imines and chiral diene ligands, with bicyclo[3.3.0]octadiene and dicyclopentadiene skeletons, in asymmetric chemical transformations. The chiral sulfinamide–olefin products from allylation of N-tert-butanesulfinyl imines can be used as hybrid ligands for transition metal-catalyzed asymmetric reactions. The efforts in the further exploration of chiral sulfur–olefin ligands are also discussed.

Graphical abstract: Recent applications of chiral N-tert-butanesulfinyl imines, chiral diene ligands and chiral sulfur–olefin ligands in asymmetric synthesis

Article information

Article type
Review Article
Submitted
28 sen 2014
Accepted
11 noy 2014
First published
18 noy 2014

Org. Chem. Front., 2015,2, 73-89

Recent applications of chiral N-tert-butanesulfinyl imines, chiral diene ligands and chiral sulfur–olefin ligands in asymmetric synthesis

H. Dong, M. Xu, C. Feng, X. Sun and G. Lin, Org. Chem. Front., 2015, 2, 73 DOI: 10.1039/C4QO00245H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements