Formation of a “pseudosuitane”-type complex between a triptycene-derived bis(crown ether) host and 1,1′-(anthracene-9,10-diyl)bis(N-benzylmethanaminium): a new method for the synthesis of linear polyrotaxanes

Fei Zeng; Zheng Meng; Ying Han; Chuan-Feng Chen

doi:10.1039/C4CC02904F

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Formation of a “pseudosuitane”-type complex between a triptycene-derived bis(crown ether) host and 1,1′-(anthracene-9,10-diyl)bis(N-benzylmethanaminium): a new method for the synthesis of linear polyrotaxanes†

Fei Zeng,^ab Zheng Meng,^ab Ying Han^a and Chuan-Feng Chen*^a

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* Corresponding authors

^a Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Molecular Recognition and Function, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
E-mail: cchen@iccas.ac.cn
Fax: +86-10-62554449

^b University of Chinese Academy of Sciences, Beijing 100049, China

Abstract

A “pseudosuitane”-type complex between a triptycene-derived bis(crown ether) host and 1,1′-(anthracene-9,10-diyl)bis(N-benzylmethanaminium) can be formed in the solution and the solid state, which provides us a new method for the synthesis of linear polyrotaxanes.

This article is part of the themed collection: Polymer Self-Assembly

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DOI: https://doi.org/10.1039/C4CC02904F
Article type: Communication
Submitted: 19 apr 2014
Accepted: 22 may 2014
First published: 23 may 2014

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Chem. Commun., 2014,50, 7611-7613

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Formation of a “pseudosuitane”-type complex between a triptycene-derived bis(crown ether) host and 1,1′-(anthracene-9,10-diyl)bis(N-benzylmethanaminium): a new method for the synthesis of linear polyrotaxanes

F. Zeng, Z. Meng, Y. Han and C. Chen, Chem. Commun., 2014, 50, 7611 DOI: 10.1039/C4CC02904F

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Chemical Communications

Formation of a “pseudosuitane”-type complex between a triptycene-derived bis(crown ether) host and 1,1′-(anthracene-9,10-diyl)bis(N-benzylmethanaminium): a new method for the synthesis of linear polyrotaxanes†

Abstract

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Formation of a “pseudosuitane”-type complex between a triptycene-derived bis(crown ether) host and 1,1′-(anthracene-9,10-diyl)bis(N-benzylmethanaminium): a new method for the synthesis of linear polyrotaxanes

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