Negative area compressibility in silver(I) tricyanomethanide

Sarah A. Hodgson; Jasper Adamson; Sarah J. Hunt; Matthew J. Cliffe; Andrew B. Cairns; Amber L. Thompson; Matthew G. Tucker; Nicholas P. Funnell; Andrew L. Goodwin

doi:10.1039/C3CC47032F

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Negative area compressibility in silver(i) tricyanomethanide†

Sarah A. Hodgson,^a Jasper Adamson,^a Sarah J. Hunt,^a Matthew J. Cliffe,^a Andrew B. Cairns,^a Amber L. Thompson,^a Matthew G. Tucker,^bc Nicholas P. Funnell^a and Andrew L. Goodwin*^a

Author affiliations

* Corresponding authors

^a Department of Chemistry, University of Oxford, Inorganic Chemistry Laboratory, South Parks Road, Oxford OX1 3QR, UK
E-mail: andrew.goodwin@chem.ox.ac.uk
Fax: +44 (0)1865 274690
Tel: +44 (0)1865 272137

^b ISIS Facility, Rutherford Appleton Laboratory, Chilton, Didcot, UK

^c Diamond Light Source, Harwell Campus, Didcot, UK

Abstract

The molecular framework Ag(tcm) (tcm⁻ = tricyanomethanide) expands continuously in two orthogonal directions under hydrostatic compression. The first of its kind, this negative area compressibility behaviour arises from the flattening of honeycomb-like layers during rapid pressure-driven collapse of the interlayer separation.

This article is part of the themed collection: 2014 Emerging Investigators

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/C3CC47032F
Article type: Communication
Submitted: 13 sen 2013
Accepted: 09 dek 2013
First published: 09 dek 2013
This article is Open Access

Download Citation

Chem. Commun., 2014,50, 5264-5266

Permissions

Request permissions

Negative area compressibility in silver(I) tricyanomethanide

S. A. Hodgson, J. Adamson, S. J. Hunt, M. J. Cliffe, A. B. Cairns, A. L. Thompson, M. G. Tucker, N. P. Funnell and A. L. Goodwin, Chem. Commun., 2014, 50, 5264 DOI: 10.1039/C3CC47032F

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications

Negative area compressibility in silver(i) tricyanomethanide†

Abstract

Supplementary files

Article information

Download Citation

Permissions

Negative area compressibility in silver(I) tricyanomethanide

Social activity

Search articles by author

Spotlight

Advertisements