Issue 75, 2012
From the journal:

Chemical Communications

Endocyclic P–P bond cleavage in carbaborane-substituted 1,2-diphosphetane: a new route to secondary phosphinocarbaboranes†‡

Anika Kreienbrink,a   Peter Lönnecke,a   Matthias Findeisenb  and  Evamarie Hey-Hawkins*a  

* Corresponding authors

a Institut für Anorganische Chemie, Universität Leipzig, Johannisallee 29, 04103 Leipzig, Germany
E-mail: hey@rz.uni-leipzig.de
Fax: +49 341-9739319

b Institut für Analytische Chemie, Universität Leipzig, Linnéstraße 3, 04103 Leipzig, Germany

Abstract

Carbaborane-substituted 1,2-diphosphetane reacts with elemental lithium and hydrogen chloride to give exclusively secondary mono- and bis(phosphino)carbaboranes. The latter reacts with two equivalents of formaldehyde and one equivalent of aniline to give a carbaborane-substituted 1-aza-3,6-diphosphepane.

Graphical abstract: Endocyclic P–P bond cleavage in carbaborane-substituted 1,2-diphosphetane: a new route to secondary phosphinocarbaboranes

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C2CC34860H
Article type
Communication
Submitted
27 apr 2012
Accepted
31 iyl 2012
First published
02 avq 2012

Chem. Commun., 2012,48, 9385-9387

Permissions

Request permissions

Endocyclic P–P bond cleavage in carbaborane-substituted 1,2-diphosphetane: a new route to secondary phosphinocarbaboranes

A. Kreienbrink, P. Lönnecke, M. Findeisen and E. Hey-Hawkins, Chem. Commun., 2012, 48, 9385 DOI: 10.1039/C2CC34860H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements