Issue 62, 2024

Synthesis of sterically congested unsymmetrical 1,2-dicarbonyl radicals through a stepwise approach

Abstract

A simplified and stepwise synthetic method for producing sterically congested unsymmetrical 1,2-dicarbonyl radicals was successfully demonstrated including detailed characterization of each radical cation. Using this approach, an aryl- and N-heterocyclic carbene-substituted 1,2-dicarbonyl radical in its neutral form is generated, revealing the stabilizing role of N-heterocyclic carbenes.

Graphical abstract: Synthesis of sterically congested unsymmetrical 1,2-dicarbonyl radicals through a stepwise approach

Supplementary files

Article information

Article type
Communication
Submitted
30 apr 2024
Accepted
05 iyl 2024
First published
05 iyl 2024

Chem. Commun., 2024,60, 8043-8046

Synthesis of sterically congested unsymmetrical 1,2-dicarbonyl radicals through a stepwise approach

Y. Song, H. Song, Y. Choi, J. Seo and E. Lee, Chem. Commun., 2024, 60, 8043 DOI: 10.1039/D4CC02092H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements