Issue 59, 2022

Gold-catalysed rearrangement of unconventional cyclopropane-tethered 1,5-enynes

Abstract

The synthesis of particular cyclopropane-tethered 1,5-enynes, namely 6-alkynyl-4-alkylidenebicyclo[3.1.0]hex-2-enes, enabled the discovery of unprecedented gold-catalyzed rearrangment to indenes. A computational study of the mechanism of this profound skeleton rearrangement is also disclosed.

Graphical abstract: Gold-catalysed rearrangement of unconventional cyclopropane-tethered 1,5-enynes

Supplementary files

Article information

Article type
Communication
Submitted
20 may 2022
Accepted
22 iyn 2022
First published
22 iyn 2022

Chem. Commun., 2022,58, 8206-8209

Gold-catalysed rearrangement of unconventional cyclopropane-tethered 1,5-enynes

R. Vicente, E. Tudela, M. A. Rodríguez, Á. L. Suárez-Sobrino and A. Ballesteros, Chem. Commun., 2022, 58, 8206 DOI: 10.1039/D2CC02869G

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