Issue 15, 2021

Single crystal to single crystal transformation of spin-crossover coordination polymers from 3D frameworks to 2D layers

Abstract

A ligand exchange induced single crystal to single crystal (SCSC) transformation from 3D Hofmann-type frameworks [Fe(ep)M(CN)4] (ep = ethylpyrazine; M = Pt, Pd) to 2D layer networks [Fe(mp)2M(CN)4] (mp = methoxypyrazine) was observed. Interestingly, the different pillar–ligands showed a significant influence on the structural assembly and spin-crossover properties.

Graphical abstract: Single crystal to single crystal transformation of spin-crossover coordination polymers from 3D frameworks to 2D layers

Supplementary files

Article information

Article type
Communication
Submitted
30 yan 2021
Accepted
18 mar 2021
First published
19 mar 2021

J. Mater. Chem. C, 2021,9, 5082-5087

Single crystal to single crystal transformation of spin-crossover coordination polymers from 3D frameworks to 2D layers

Y. Gong, W. Han, H. Lu, Q. Hu, H. Tu, P. Li, X. Yan and Z. Gu, J. Mater. Chem. C, 2021, 9, 5082 DOI: 10.1039/D1TC00470K

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