Issue 27, 2020

Ice-assisted synthesis of functional nanomaterials: the use of quasi-liquid layers as nanoreactors and reaction accelerators

Abstract

The discovery of peculiar quasi-liquid layers on ice surfaces marks a major breakthrough in ice-related sciences, as the facile tuning of the reactions and morphologies of substances in contact with these layers make ice-assisted chemistry a low-cost, environmentally benign, and ubiquitous methodology for the synthesis of nanomaterials with improved functionality. Ice-templated synthesis of porous materials offers the appealing features of rapid self-organization and remarkable property changes arising from confinement effects and affords materials that have found a diverse range of applications such as batteries, supercapacitors, and gas separation. Moreover, much attention has been drawn to the acceleration of chemical reactions and transformations on the ice surface due to the freeze concentration effect, fast self-diffusion of surface water, and modulated surface potential energy. Some of these results are related to the accumulation of inorganic contaminants in glaciers and the blockage of natural gas pipelines. As an emerging theme in nanomaterial design, the dimension-controlled synthesis of hybrid materials with unprecedentedly enhanced properties on ice surfaces has attracted much interest. However, a deep understanding of quasi-liquid layer characteristics (and hence, the development of cutting-edge analytical technologies with high surface sensitivity) is required to achieve the current goal of ice-assisted chemistry, namely the preparation of tailor-made materials with the desired properties.

Graphical abstract: Ice-assisted synthesis of functional nanomaterials: the use of quasi-liquid layers as nanoreactors and reaction accelerators

Article information

Article type
Review Article
Submitted
02 apr 2020
Accepted
18 may 2020
First published
19 may 2020

Nanoscale, 2020,12, 14320-14338

Ice-assisted synthesis of functional nanomaterials: the use of quasi-liquid layers as nanoreactors and reaction accelerators

K. Kim and M. J. Park, Nanoscale, 2020, 12, 14320 DOI: 10.1039/D0NR02624G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements