Issue 75, 2020

Redox-regulated divergence in photocatalytic addition of α-nitro alkyl radicals to styrenes

Abstract

A divergent photocatalytic system for the reaction of α-bromo nitroalkanes with styrene derivatives is established, wherein the generation of the persistent nitroxyl radical as a junctional intermediate and suitable tuning of the redox ability of the system constitute the crucial elements for achieving rigorous control over the possible reaction pathways.

Graphical abstract: Redox-regulated divergence in photocatalytic addition of α-nitro alkyl radicals to styrenes

Supplementary files

Article information

Article type
Communication
Submitted
13 iyl 2020
Accepted
03 avq 2020
First published
04 avq 2020

Chem. Commun., 2020,56, 11014-11017

Author version available

Redox-regulated divergence in photocatalytic addition of α-nitro alkyl radicals to styrenes

Y. Tsuchiya, R. Onai, D. Uraguchi and T. Ooi, Chem. Commun., 2020, 56, 11014 DOI: 10.1039/D0CC04821F

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