Issue 25, 2019

The formation of a 1,4-disilabenzene and its isomerization into a disilabenzvalene derivative

Abstract

A stable 1,4-disilabenzene was generated from the reaction of a stable disilyne with 3-hexyne. Its photochemical isomerization afforded the corresponding disilabenzvalene, which was structurally characterized by a single-crystal X-ray diffraction analysis.

Graphical abstract: The formation of a 1,4-disilabenzene and its isomerization into a disilabenzvalene derivative

Supplementary files

Article information

Article type
Communication
Submitted
28 mar 2019
Accepted
17 may 2019
First published
17 may 2019

Dalton Trans., 2019,48, 9053-9056

The formation of a 1,4-disilabenzene and its isomerization into a disilabenzvalene derivative

T. Sugahara, T. Sasamori and N. Tokitoh, Dalton Trans., 2019, 48, 9053 DOI: 10.1039/C9DT01322A

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